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Home » Products » TSS-ARKS - CISP(R) The analog-free software for thermal hazard assessment » ARKS CK - software for evaluation of concentration-based Kinetic models
ARKS CK - software for evaluation of concentration-based Kinetic modelsPurpose of the program The ARKS CK (Descriptive concentration-based kinetics) software is intended for creation of complex multi-stage descriptive concentration-based kinetic models on the basis of available sets of experimental data generated by methods of thermal analysis, adiabatic and reaction calorimetry. In addition the program provides fast and reliable simulation of processes in a well stirred BATCH, semi-BATCH, continuous stirred (CSTR) and plug-flow (PFR) reactors. Kinetics evaluation is implemented by employing the state-of-the-art nonlinear optimization method. The group or mutually complementary robust numerical integration methods allows accurate integration of the stiff system of ordinary differential equations that represent a model. It should be specifically noted that the most appropriate data for creation of concentration-based models can be obtained by applying reaction calorimetry ((Mettler RC1, HEL Simular, ChemiSens CPA 102, 202 and many others), which provides accurate information about heat generation by a reaction coupled with data on variation of mixture composition. The convenient project-oriented interface facilitates ARKS CK application. ARKS CK is addressed to those who are interested in reaction kinetics, to chemical engineers involved in design of chemical processes, to specialists in thermal hazard assessment of processes, etc. ARKS CK comprises two main modules – Simulation and Estimation. The access to these modules is provided by the ARKS CK suite shell which makes use of the package more convenient and vivid. The unique feature of the software is that it uses the specialized method of statistical analysis for estimation of the quality of a model created. The ARKS CK software inherits the best qualities of its predecessor DesK and has many new features - new interface, revised and improved algorithms, completely reworked documentation, etc. ARKS CK is supported by videotutorils which help in mastering software:
Loading data ARKS CK allows handling multi response data containing integral and/or derivative responses: heat, gas generation, pressure and concentrations of species. ARKS CK provides direct access to experimental data stored in ARKS-AC and ARKS TA databases for importing data. Note that in the case of data from reaction calorimetry there is no need in data transfer of any kind between ARKS CK and ARKS RC - they use common data base. The possibility is also envisaged to paste responses from clipboard. Storing data ARKS CK stores original and processed data into internal database. Database consists of data volumes. Every data volume includes number of data sets; each data set may represent results of separate run, simulated results, conditions of an experiment, and kinetic model created. ARKS CK allows saving estimation projects. Every project includes all the information prepared for estimating kinetic parameters - kinetic model, initial guess on parameters and their limits, references to experimental data sets, etc. Physical properties ARKS CK supports two sources of physical properties necessary for simulation:
Type of kinetic models ARKS CK supports application of complex multi stage descriptive kinetic models that are based on concentrations as state variables and obey the generalized Law of Mass Action. Creation of a model is implemented by defining the stochiometric scheme of a reaction. No programming is required. See CISP Newsletter N6 for more details Reactor’s model A chemical reaction is considered to proceed in a continuous stirred tank reactor (CSTR) which can operate under the following thermal modes:
Simulation module provides modeling of a reaction's behavior. The following possibilities are envisaged:
Estimation module is used for estimation of kinetic parameters when evaluating chemical kinetics. The following possibilities are envisaged:
Installation Requirements: CPU: Intel Pentium 1200 MHz and faster; Memory: 1024 MB; Disk space: 50 MB, CD-ROM: present ATTENTION! 1. When installing ARKS CK under Windows 7 and higher we strongly recommend to use the default path 2. When installing TSS-ARKS applications one can meet the problem with Anti-virus tools you use. Be aware - even if you are the licensed user of TSS or TSS-ARKS software with valid guarantee or maintenance when you upgrade DesK to ARKS CK you will have to get new registration key. Please email us the request and don't forget to indicate your company and your name IMPORTANT! Be aware that on the expiration of the Warranty/maintenance Period the License on any TSS or TSS-ARKS application remains valid for the version last updated during maintenance Period. Therefore if your maintenance has expired you wouldn't be able to use new updates. If you nevertheless download the setup of new version and replace your working version with new one it won't work and you will lose working program! To avoid such situation check please whether you have valid maintenance before downloading any TSS-ARKS program. |